水環境学会誌
Online ISSN : 1881-3690
Print ISSN : 0916-8958
ISSN-L : 0916-8958
原著論文
ハイドロタルサイト化合物を配合したコンクリートブロックによる都市河川からのリン除去
桑原 智之佐藤 利夫野中 資博山本 広基相崎 守弘福田 康伴
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ジャーナル フリー

2004 年 27 巻 2 号 p. 109-115

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Concrete blocks with phosphorous adsorption ability have been developed to remove non-point source phosphorous from rivers and canals. The concrete blocks were prepared by mixing cement with a hydrotalcite compound (HT) that has high selectivity and large phosphorous adsorption capacity. The concrete blocks (test pieces) with various the filling ratios of 85, 90 and 95% were prepared using fresh concrete, and the result of the slump test was 0 cm. Also, the compressive strength and phosphorous removal capacity were investigated fundamentally. The results showed that the compressive strength of all the test pieces was above 18N·mm-2 and they were sufficiently strong for use as laying blocks. For a test piece with a low filling ratio, phosphorous was removed by Ca2+ and for a test piece with a high filling ratio, phosphorous was not removed by ion exchange. However, these results suggest that high strength and high phosphorous adsorption ability are compatible with each other, which can be controlled by regulating the mix proportion. Furthermore, field tests were conducted using large concrete blocks containing HT (HT specimens). The results showed that phosphorous was adsorbed at the uppermost layer of the HT specimens. In the tests, the break-through of phosphorous adsorption occurred three months later and the average removal rate for such break-through was 3.69mg P·m-2·d-1.

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© 2004 公益社団法人 日本水環境学会
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