水環境学会誌
Online ISSN : 1881-3690
Print ISSN : 0916-8958
ISSN-L : 0916-8958
技術報告
メチルイソチオシアネートの水域環境における分解挙動
片桐 和臣柚木 雅子小川 早苗中園 金吾下川 裕子吉田 智彦茅島 孝和廣松 康一立山 隆夫西原 力
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ジャーナル フリー

2009 年 32 巻 4 号 p. 213-218

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Methyl isothiocyanate (MITC) is a fumigant used to control nematodes, fungi, and insects in agricultural soils. Most of MITC used for agriculture is released into the environment. To examine the degradation behavior of MITC in an aquatic environment, a biodegradation test using an activated sludge was carried out. This test revealed that MITC is hardly mineralized, but converted to six metabolites, which were determined to be 1,3-dimethylthiourea, 3-methylamino-5-oxa- thia-2,7-diaza-2,6-octadiene, 3-methylamino-4,5-dithia-2,7-diaza-2,6-octadiene, methylamine, elemental sulfur, and carbon disulfide. The first three compounds have never been detected or predicted as products even in soil.
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© 2009 公益社団法人 日本水環境学会
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