2001 Volume 42 Issue 12 Pages 2576-2583
The exothermic reaction occurring after β′′ precipitation in Al–Mg–Si alloys has been investigated by means of differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The reaction peak height observed in DSC increases with increasing excess Mg or decreasing excess Si content from Al–Mg2Si quasi-binary composition. It was confirmed that this reaction peak arises from the precipitation of cuboid β-Mg2Si particles related to the matrix with the cube-cube orientation relationship. At the later stage of ageing, thin β-Mg2Si plates nucleate at the cuboid β-phase particles. The orientation relationship of them is rotated 45° or 18.4° in the further aged specimens about the direction normal to the {001}Al||{001}β habit plane from the cube-cube relationship. The changes in morphology and the crystallography of the β-Mg2Si precipitates with the progress of ageing can be explained qualitatively in terms of coherency and interface energy of the precipitates.