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Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678

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Dealloying of Cu-Zr-Ti Bulk Metallic Glass in Hydrofluoric Acid Solution
Hiroya AbeKazuyoshi SatoHiroshi NishikawaTadashi TakemotoMikio FukuharaAkihisa Inoue
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JOURNAL RESTRICTED ACCESS Advance online publication

Article ID: ME200823

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Abstract
The dealloying behavior of Cu60Zr30Ti10 metallic glass was investigated under free corrosion conditions using hydrofluoric acid (HF) solutions at room temperature. After immersing in HF solutions with various concentrations (0.05, 0.1, 0.5 and 1 M) for 300 s, color of all samples changed to be pinkish or peachy, which was ascribed to Cu based on the XRD patterns. According to the SEM-EDS study, HF immersion selectively leached the Zr and Ti elements, leaving Cu behind. Increasing the HF concentration increased the dealloying rate. Moreover, the HF concentration strongly influenced the surface morphology of the resulting Cu.
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© 2009 The Japan Institute of Metals and Materials
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