日本化学会誌(化学と工業化学)
Online ISSN : 2185-0925
Print ISSN : 0369-4577
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アパタイト型Ndx(SiO4)6O1.5x−12単結晶のEPMAによって決定された組成と伝導率の関係
中山 享樋口 幹雄上松 和義
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2002 年 2002 巻 2 号 p. 243-245

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Four kinds of single crystals of hexagonal apatite type Ndx(SiO4)6O1.5x−12 (x = 8–9.33), which is an oxide ionic conductor, were prepared by the FZ method and samples for electrical measurements (the conductivity components parallel and perpendicular to the c-axis of single crystal) were prepared. The conductivities of the component parallel to the c-axis were higher about one order of magnitude, compared with those of the component perpendicular. The values of (Nd/Si) × 6 of four kinds of samples were 8.63, 8.67, 8.91 and 9.33 determined by electron probe micro-analysis. The conductivity was slightly increased with decreasing the value of (Nd/Si) × 6.
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© 2002 The Chemical Society of Japan
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