Grignard 試薬のカルボキシル化によるカルボン酸合成の別法

抄録

An alternative method for carboxylation of the Grignard reagents was developed. Both aromatic and aliphatic Grignard reagents gave the corresponding carboxylic acids in moderate yields by the reaction with pentacarbonyliron followed by treatment with iodine-water. The secondary alkyl Grignard reagents gave the acids rather in low yields.