Co₂(CO)₈-ジホスフィン触媒による酢酸アリルおよびギ酸アリルの均一ヒドロホルミル化反応

抄録

Some Co₂(CO)₈-diphosphine catalysts were found to be effective for the hydroformylation of aClHlyPl Phacetate and allyl formate; the activity decreased in the order: diphos>cis -Ph₂PCH=CHPPh₂>Ph₂PC=CPPh₂> none >Ph₂PCH₂PPh₂ > PPh₃. Under the conditions employed, 4-acetoxybutanal was 80% or above of three isomeric aldehydes produced.