日本セラミックス協会 年会・秋季シンポジウム 講演予稿集
16th Fall Meeting of The Ceramic Society of Japan & The 5th International Meeting of Pacific Rim Ceramic Societies(PacRim5)
セッションID: 06-P-03
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Fabrication and Characterization of Ca-Subsituted Sr2(Nb,Ta)2O7 Thin Film by Chemical Solution Deposition Method
*Yukinobu YURAToshiaki YAMAGUCHIWataru SAKAMOTOKoichi KIKUTAShin-ichi HIRANO
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Recently, ferroelectric random access memory (FeRAM) with a metal/ ferroelectric/ metal/ insulator/ semiconductor field-effect transitors (MFMIS-FET) structure have been studied extensively because of various advantages such as the miniaturization of memory cell and non-destructive read out.In order to attain the sufficient application of external voltage to ferroelectrc layer, ferroelectrics need to have low dielectric constant. Sr2(Nb,Ta)2O7 type compound is one of the candidates for ferroelectric layer in MFMIS-FET structure because of its low dielectric constant and Pb- and Bi-free composition. In this work, fabrication and characterization of Ca-substituted Sr2(Nb,Ta)2O7 thin films on various substrates could be carried out by chemical solution deposition method. Homogeneous and stable precursor solutions were prepared by controlling the reaction of starting metal alkoxides. (Sr,Ca)2(Nb,Ta)2O7 thin films could successfully be synthesized with high crystallinity on Pt/ Ir/ Ti/ SiO2/ Si substrates. Electrical properties of prepared (Sr,Ca)2(Nb,Ta)2O7 thin films were also evaluated.
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© The Ceramic Society of Japan 2003
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