抄録
In this paper, photoelectron effect is applied to describe the reaction mechanism of macroscopic orderly stacking new crystalline from the poly(oxypropylene)amine modified clays. With X-ray fluorescent irradiates the condensed film of poly(oxypropylene)amine intercalated smectite silicates, a special inhomogeneous Si photoelectron (102.1 electron volts) concentration pattern was revealed. Silicone with shifted electron binding energy on the surface of the organo-silicates causes the photoelectron energy differentiated. Analysis of the FTIR vibration spectrums show no new chemical bonding assigned to the organo-silicate condensation. It is proposed the radius of ionic outer shell of silicone was altered as the poly(oxypropylene)amine intercalated montmorillonite proceeding a organo-mineral polymerization by self assembly process. Optical polarized microscope and X-ray diffraction pattern also confirmed the transformation of random particulate to a special nematic texture of organo-clay hybrid polymer.
