Journal of Photopolymer Science and Technology
Online ISSN : 1349-6336
Print ISSN : 0914-9244
ISSN-L : 0914-9244
Oxime Type Photoacid Generators Having Adamantyl and Superstrong Acid Precursor Group
Masumi YamamotoShigeru Takahara
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2018 年 31 巻 5 号 p. 643-646

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Oxime derivatives, having a N-O bond in the molecule structure, are excellent photo reactive compounds. Oxime type photoacid generaters with adamantyl and perfluoroalkylsulfonyloxy groups and without aromatic groups were prepared, and their absorption spectra and thermal properties were measured. The compounds designed with photoacid generator in deep ultraviolet (DUV) region have good transparency in the region. The thermal stability of these PAGs depended on the chain length of acid precursor groups. The quantum yields of acid generation were substantially high. These aliphatic oxime sulfonates can be expected to be PAGs in DUV.
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© 2018 The Society of Photopolymer Science and Technology (SPST)
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