Synthesis and Reactions of Poly (N-allenylpyrrolidone) Having Adsorption Functions

抄録

For the synthesis of reactive polymers with high adsorption abilities, poly (N-allenylpyrrolidone) was prepared by the radical polymerization of N-allenylpyrrolidone in bulk or in ethanol solution using 2, 2'-azobis (isobutyronitrile) (AIBN) as an initiator at 60°C. The resulting polymer was subjected for the radical addition reaction with dodecanethiol to give the docecylmercapto-grafted poly (N-allenylpyrrolidone). Radical polymerization of vinyl acetate was carried out in the presence of poly (N-allenylpyrrolidone) to obtain poly (vinyl acetate) -grafted poly (N-allenylpyrrolidone).