粉体工学会誌
Online ISSN : 1883-7239
Print ISSN : 0386-6157
ISSN-L : 0386-6157
論文
複合粒子により作製された SOFC カソードの電極特性評価
近藤 光Cheng-Yen Hsu小澤 隆弘内藤 牧男
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2016 年 53 巻 6 号 p. 380-385

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The composite particles were prepared by one-step mechanical processing of the starting raw powders of La0.8Sr0.2MnO3 (LSM) and scandia stabilized zirconia (ScSZ) fine particles. In this paper, volume percentage of ScSZ in composite particles was set as 50 vol% and 62 vol%, respectively. The SOFC cathodes using the composite particles were prepared by sintering at 1200℃. Sintering time was selected as 2h and 3h. As results of electrochemical examinations by AC impedance measurements, the increased content of ScSZ (62 vol%) and the shorter sintering time (2h) contributed to improving the polarization resistance (Rp) of cathodes. Three factors such as conductivity of oxygen ion, formation of triple phase boundaries and gas diffusivity were discussed for the improvement of Rp using the Bode plots which showed the relationship between the absolute value of imaginary part of impedance and the frequency.
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