日本塩学会誌
Online ISSN : 2187-0322
Print ISSN : 0369-5646
ISSN-L : 0369-5646
ポリヘキシルの合成について (第2報)
ニトロポリスチレンよりポリヘキシルに至る反応
斎藤 進飯島 正明
著者情報
ジャーナル フリー

1958 年 12 巻 1 号 p. 15-19

詳細
抄録
With connection to the previous papers, we inform here the synthetic methods of polyhexyl and per properties. p-Mononitropolystyrene seported in the previous papers, is reduced by sodium sulfide an aut oclave about 150°C to p-aminopolystyrene and the latter condenses with picrylchloride in vridine forming Picryl-p-Aminopolystyrene. Still more picryl-p-aminopolystyrene is nitrated by a mixed acid of nitric and nitric fuming to polyhexyl. This compound or resin is refined by dealing with 0.2 N NaOH and 0.2N H2SO4 continuously. This absorbs almost 100 % potassuim ions of calculated values and the selectivity curve in Na-K-Cl system is shown in Fig-2.
著者関連情報
© 日本海水学会
前の記事 次の記事
feedback
Top