抄録
We report effects of washing rubbed polyimide film on the near surface. Especially we focused dependence of solvent. Rubbed polyimide films have been used as liquid crystal alignment films in Liquid crystal displays (LCDs), and in actual LCD panel fabrication washing on film surfaces after rubbing is essential process to remove dust and pollution. We investigated the effects of washing by grazing incidence X-ray diffraction (GIXD) measurements. In GIXD, the X-ray penetration into the polymer was changed from 8nm (suface sensitive) to 4nm (bulk sensitive) by variation of the X-ray incidence angle. It was found that crystallization near the surface induced by soaking was considerably dependent on solvent. However, in-plane distribution of the surface polymer chains of polyimide film was not found to be dependent on the solvents.
