VITAMINS
Online ISSN : 2424-080X
Print ISSN : 0006-386X
ON THE SODIUM SALT OF FLAVINADENINEDINUCLEOTIDE
Yoneo MIYAZAKITaiji MORITAJiro MIYASHITATadashi ISHIDAYutaka YAMAWAKIKazuyuki TSUJI
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1962 Volume 26 Issue 4 Pages 275-278

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Abstract
It was discussed about the sodium salt of FAD in this paper. Sodium was estimated colorimetrically as the zinc uranyl acetate complex and also titrimetrically as the sodium chloride isolated with Amberlite IR-120. Hydrate was determined with Karl-Fischer method. The stoichiometric point of the sodium salt of FAD as determined by the potentiometric titration curve was about 6. The curve presented clearly shows that two moles of sodium hydroxide united with one mole of FAD resulting in the break of the curve at pH 6. The dissociation constants, K_1 and K_2,were 7.6×10^<-4> and 6.0×10^<-5>, respectively. Inspection of the data shows that the sodium salt of FAD, when dried in vacuum desiccator over phosphorus pentoxide at room temperature, is FAD disodium salt dihydrate (C_<27>H_<31>N_9O_<15>P_2.Na_2.2H_2O).
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© 1962 THE VITAMIN SOCIETY OF JAPAN

この記事はクリエイティブ・コモンズ [表示 - 非営利 - 改変禁止 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
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