ビタミン
Online ISSN : 2424-080X
Print ISSN : 0006-386X
ビタミンB_1と金属との関係についての研究 : (III)ビタミンB_1と1価銅との反応について
山根 靖弘宮崎 元一本宮 幸子深谷 啓子
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ジャーナル フリー

1967 年 36 巻 2 号 p. 134-136

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抄録
The first paper of this series showed that the red fluorescent product was formed by reaction of thiamine with Cu^<2+>, and could be applied to the detection of the vitamin. The second report dealt with the reaction products between thiolized thiamine and Cu^<2+>, Cd^<2+> or Zn^<2+>, respectively. The molar ratio of metal to thiamine of the product was found to be 1 : 2. In this paper, the reaction between thiolized thiamine and Cu^+ was dascribed. The reaction product had a brilliant and stable red fluorescence and the molar ratio of Cu^* to thiamine was found to be 1 : 1. It is supposed that the reaction product is a metal chelate compound by the examination of ultraviolet and infrared spectura.
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© 1967 日本ビタミン学会

この記事はクリエイティブ・コモンズ [表示 - 非営利 - 改変禁止 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
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