2018 年 34 巻 p. 1-2
A mononuclear iron(III) complex [FeCl(dmso)5](BPh4)2 [chloridopentakis(dimethylsulfoxide-κO)iron(III) bis(tetraphenylborate)] was synthesized, and characterized by a single-crystal X-ray method. The compound crystallized in the monoclinic space group P21/n and Z = 2 with cell parameters a = 10.4961(16)Å, b = 14.260(2)Å, c = 19.166(3)Å, β = 94.512(2)°, V = 2859.8(7)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values were 0.1149 and 0.2930, respectively, for all 6552 independent reflections. The analysis revealed an octahedral geometry with ClO5 donor set.