Crystal Structure of a Mononuclear Iron(III) Complex, Hexakis(dimethylsulfoxide-κO)iron(III) Tris(hexafluoridophosphate)

Kaoru SHOMURA; Ryoji MITSUHASHI; Masahiro MIKURIYA; Yusuke KATAOKA; Makoto HANDA; Hiroshi SAKIYAMA

doi:10.2116/xraystruct.35.31

Part 5

Crystal Structure of a Mononuclear Iron(III) Complex, Hexakis(dimethylsulfoxide-κO)iron(III) Tris(hexafluoridophosphate)

Kaoru SHOMURA, Ryoji MITSUHASHI, Masahiro MIKURIYA, Yusuke KATAOKA, Makoto HANDA, Hiroshi SAKIYAMA

著者情報

ジャーナルフリー
電子付録

2019 年 35 巻 p. 31-32

DOI https://doi.org/10.2116/xraystruct.35.31

詳細

抄録

A mononuclear iron(III) complex, [Fe(dmso)₆][PF₆]₃ [hexakis(dimethylsulfoxide-κO)iron(III) tris(hexafluoridophosphate)], was synthesized, and characterized by a single-crystal X-ray method. The compound crystallized in the trigonal space group R3 and Z = 3 with cell parameters a = 11.598(8)Å, c = 25.367(18)Å, V = 2955(4)Å³. The R₁ [I > 2σ(I)] and wR₂ (all data) values were 0.0509 and 0.1565, respectively, for all 1630 independent reflections. The symmetry of the complex cation was found to belong to the S₆ point group, possessing a trigonally compressed octahedral coordination geometry with an O₆ donor set.

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