Development of Heteroatom-introducing Methodologies Based on Ate Complex Formation: Perfluoroalkylation, Borylation, Aromatic Hydroxylation, and Amination Reactions

Abstract

 We have developed regio- and chemoselective heteroelement-introducing reactions based on ate complex formation. This review is focused on novelly designed reactive species for efficient access to perfluoroalkylated aliphatic and aromatic compounds as well as Csp²-borylated compounds.