YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Preparation of the Stiryl- and Iso-cyanine Dyes from Quarternary Quinoline Derivatives
Masujiro Katayanagi
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1948 Volume 68 Issue 3-4 Pages 133-136

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Abstract
During the course of the prepartion of styryl- and isocyaninedyes with 4-phenoxyquinaldine methiodide, the reaction does not occur when the amount of the catalyst amine is small. In an aqueous solution, only the phenoxy radical at 4-position is substituted by the secondary amine, but in alcoholic solution, methyl radicals at both 2- and 4-positions are activated. Use of excess of tertiary amine decomposes styryl dye which transits to isocyanine dye.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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