鹽基性フエノールアルキルエーテル類の合成 (續報 7)
1949 年 69 巻 5 号 p. 228-230
詳細
1949 年 69 巻 5 号 p. 228-230
1) Reduction of bromacetone by Al-ethoxide gives ω-bromo-isopropyl alcohol, application of diethylamine to which gives ω-diethylamino-isopropyl alcohol.
2) Following compounds were synthesized from C-allylguaiacol: symm.-Bis-diethylamino-isopropyl 2-methoxy-6-allylphenyl ether, b.p.12 199°; β-Hydroxy-γ-diethylaminopropyl 2-methoxy-6-allylphenyl ether, b.p.5 160°, β-Methoxy-γ-diethylaminopropyl 2-methoxy-6-allylphenyl ether, b.p.15 213-5°, and β-Allyloxy-γ-diethylaminopropyl 2-methoxy-6-allylpheny ether b.p.9 197°.
