YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Studies on the Components of Rhodea japonica Roth. III
Structure of Rhodexin A and Rhodexin B
Hayao Nawa
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1952 Volume 72 Issue 3 Pages 410-414

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Abstract
From the results obtained in the previous report (v.s.), the aglycone of rhodexin A is assumed to be sarmentogenin whose isolation from rhodexin A was successfully carried out by the Mannich method. Hydrolysis of rhodexin B with diluted alcohol containing 3.3% of hydrochloric acid yielded dianhydrorhodexigenin B which coincides with dianhydrogitoxigenin. The sugar obtained by the hydrolysis of rhodexin B was found to be rhamnose from its paper partition chromatogram and the phenylosazone. From these results, rhodexin B is assumed to be a new glycoside possessing gitoxigenin as an aglycone and rhamnose as its sugar.
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