YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Rôle of Chromium Oxide in the Reduction of Carboxyl Group under High Pressure Hydrogen. I
Hiroshi HasegawaRyoichi Miyake
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1953 Volume 73 Issue 2 Pages 187-190

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Abstract
The chromium oxide formed by the thermal decomposition, at 350°, of ammonium chromium chromate prepared from chromium salt and chromate, is a mixture of chromium oxides which can be indicated by CrO2. This chromium oxide was used as a catalyst in the high pressure acid reduction of camellia oil in nichrome autoclave but the oxide did not seem to possess any catalytic activity. However, under the present experimental conditions, the inner wall of the autoclave seemed to induce some side reactions so that the above conclusions should be checked by different experimental apparatus. Infrared absorption spectral measurements indicated the presence of a fair amount of ketones and hydrocarbons as the products of side reaction.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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