YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Studies on the Friedel-Crafts Reaction of Diphenyl Ether Derivatives. VIII
Reaction of p, p′-Ditolyl Ether and Acid Chlorides
Shoshichiro Kimoto
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1955 Volume 75 Issue 5 Pages 501-505

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Abstract
It has been clarified that the application of acetyl or propionyl chloride to p, p′-ditolyl ether, in the presence of aluminum chloride, results in intermediate formation of the corresponding 2, 7-dimethyl-9-alkylxanthenol and that the reaction proceeds further with occurrence of various side-reactions. In this case, application of phenylacetyl chloride was found to give 2, 7-dimethyl-9-benzalxanthene, m.p. 103-105°, in a good yield.
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