YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
過硫酸塩の研究 (第3報)
芳香族カルボン酸類の酸化
堀井 善一桜井 謙一
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ジャーナル フリー

1957 年 77 巻 1 号 p. 1-2

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By heating aromatic amino acids in aqueous solution of potassium persulfate, corresponding carbonyl compounds were obtained (Table I). In the case of DL-phenylglycine, benzaldehyde was obtained in a good yield of 77%, indicating that the reaction proceeded easily through the same route as with carbinols. The same reaction carried out with phenylacetic acid was found to form a dimter, diphenylethane, apart from the carbonyl compound. These results are interesting in that they suggest a kind of radical reaction taking place in an aqueous solution.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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