アセチレン系化合物の研究 (第2報)
酸化反応 その2プロパルギル位メチレンの酸化
1958 年 78 巻 11 号 p. 1252-1255
詳細
1958 年 78 巻 11 号 p. 1252-1255
Oxidation of 3-phenylpropyne, 1, 3-diphenylpropyne, and 1-phenyl-2-heptyne with tert-butyl chromate or freshly sublimed selenium oxide results in the formation of corresponding acetylenic ketones, 3-phenylpropyn-3-one, 1, 3-diphenylpropyn-3-one, and 1-phenyl-2-heptyn-1-one. Oxidation of 1-hexyne and 1-phenyl-1-butyne with selenium dioxide gives the corresponding acetylenic alcohols, 1-hexyn-3-ol and 1-phenyl-1-butyn-3-ol,
