YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
フェニルピラゾロン誘導体の合成研究 (第13報)
ピラゾロンアゾメチン誘導体の吸収スペクトルに及ぼす溶媒効果について その1
板野 公平
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ジャーナル フリー

1958 年 78 巻 2 号 p. 164-167

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Solvent effect on the ultraviolet and visible absorption spectra of 14 kinds of pyrazolone-azomethine derivatives was examined. These were compounds possessing a substituent with -SO2NH- in 3-position of pyrazolone ring or those without such a substituent. In both, maximum wave length of the x-band tended to shift to a longer wave-length side with the increase of dielectric constants. The compounds with a substituent of -SO2NH- in 3-position greatly affect the resonance system by the dissociation of -SO2NH- in a basic buffer solution and the band makes a hypsochromic shift.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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