YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Syntheses of dl-1, 2-Methylenedioxy-8, 9, 10-trimethoxyaporphine and dl-1, 2, 8, 9, 10-Pentamethoxyaporphine
Kentaro Hirai
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1960 Volume 80 Issue 5 Pages 608-612

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Abstract
dl-1, 2-Methylenedioxy-8, 9, 10-trimethoxyaporphine (III) and dl-1, 2, 8, 9, 10-pentamethoxyaporphine (IV) were prepared and their characteristic ultraviolet absorption spectra (Fig. 1) were clarified. As by-products of the Pschorr reaction, benzylisoquinolinetype bases were isolated as dl-1-(2, 3, 4-trimethoxybenzyl)-2-methyl-6, 7-methylenedioxy-1, 2, 3, 4-tetrahydroisoquinoline (XVIII) and dl-1-(2, 3, 4-trimethoxybenzyl)-2-methyl-6, 7-dimethoxy-1, 2, 3, 4-tetrahydroisoquinoline (XXIV).
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