Abstract
Application of cyclohexylamine, in an amount 1.5-2 times the theoretical quantity, to ammonium nitridotrisulfate and heating the mixture at 170° for 3 hours results in formation of cyclohexylammonium cyclohexanesulfamate in over 90% yield. The amount of ammonia evolved was examined in the reaction of ammonium nitridotrisulfate and cyclohexylamine at 120° and this reaction was considered to be in a following manner:
N(SO3NH4)3+C6H11NH2=N(SO3NH4)2(SO3HC6H11NH2)+NH3
N(SO3NH4)2(SO3HC6H11NH2)+3C6H11NH2=NH(SO3HC6H11NH2)2+C6H11NHSO3HC6H11NH2+2NH3
