フェノチアジン誘導体の合成研究 (第4報)
3-ヒドロキシイミノ-3H-ピリド [3,2,1-kl] フェノチアジン誘導体のLiAlH4による還元
1962 年 82 巻 7 号 p. 992-998
詳細
1962 年 82 巻 7 号 p. 992-998
Reduction of 3-hydroxyimino-1, 2-dihydro-3H-pyrido [3, 2, 1-kl] phenothiazine with lithium aluminium hydride afforded 3-amino-1, 2-dihydro-3H-pyrido [3, 2, 1-kl] phenothiazine as the normal reduction product and 1, 2, 3, 4-tetrahydro-[1, 4]-diazepino [3, 2, 1-kl] phenothiazine as the rearrangement product. The structure of these compounds was confirmed through their synthesis.
