Phenylglcidyl Ether誘導体の研究(第6報)Phenoxypropylene Sulfideに対するAmineおよびGrignard試薬の反応

抄録

The amine-cleavage of 3-phenoxy-1, 2-propylene sulfides (II) synthesized from P.G.E. (I) with KSCN gave only sec-thiol derivatives. A mixture of sec-thiol and prim-thiol derivatives was obtained by the reaction of II with ethylmagesium bromide. The reaction of II with Grignard reagents containing more than three carbons afforded sec-thiol derivatives. The reaction product of ο-nitro-substituted II with Grignard reagents was identified as prim-thiol derivatives.