YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
水素化リチゥムアルミニゥムによるVinylogous Esterの還元(第7報) : α-Alkoxyl基置換6員環Vinylogous Esterに関して
的場 勝英浜島 健二山崎 高応
著者情報
ジャーナル フリー

1974 年 94 巻 11 号 p. 1459-1467

詳細
抄録
2-Ethoxy-3-methoxy-2-cyclohexenone (II) and 2, 3, 5-trimethoxy-2-cyclohexenone (III) were prepared from pyrogallol in a satisfactory yield. II was reduced with lithium aluminium hydride to 2-ethoxy-3-methoxy-2-cyclohexenol (XXV), which was not so stable. III was reduced under the same condition to 2, 5-dimethoxy-2-cyclohexenol (XXIX) and 2, 3, 5-trimethoxy-2-cyclohexenol (XXX). XXX was relatively stable but was not so stable as the reduced product of acutumine (I).
著者関連情報
© by the PHARMACEUTICAL SOCIETY OF JAPAN
前の記事 次の記事
feedback
Top