有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
バイオレットレーザー対応高感度増感色素の開発—フォトポリマーCTPへの応用と工業化—
渋谷 明規國田 一人
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2014 年 72 巻 1 号 p. 51-57

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A highly sensitive photopolymerization system by using violet laser, 405 nm, was investigated. The photopolymerization composition which contained an initiator and a high fluorescent dye showed efficient sensitization of the system. The photosensitization mechanism seemed to have a singlet energy transfer process. A key molecular design of the dye getting the higher photosensitization efficiency is a repression of thermal relaxation from the excitation state. The photopolymerization system was applied to the computer to plate (CTP) technology, a digital printing plate, to develop our i-Presso P-NV for the violet laser. As compared with a system using a conventional FD-YAG laser, the P-NV system revealed the advantage of high productivity on plate making and also handling under a brighter safelight.

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