有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
SmI2-H2O系を用いたエステルの電子移動還元に基づく有機合成反応
中島 一成
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ジャーナル オープンアクセス

72 巻 (2014) 2 号 p. 183-184

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In this short review, reductive transformations of esters with SmI2-H2O system are described. Recently, reduction of esters into the corresponding alcohols and intramolecular cyclization of radical anions derived from single electron reduction of esters have been extensively studied as novel and efficient methods for organic syntheses. In these reactions, a single electron transfer from SmI2 to ester is a key step, which is promoted by addition of H2O.

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© 2014 社団法人 有機合成化学協会
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