Experiments on the partitioning of Mg
2+, Ca
2+, Mn
2+, Fe
2+, Co
2+, Ni
2+ and Zn
2+ between olivine (forsterite and fayalite) and 2 N aqueous chloride solutions were performed in the temperature range of 500 to 800°C, 1 kb.
The partition coefficient, which is defined as
KPN(Fo)=(
XMe2SiO4/
XMg2SiO4)/(
mMeCl2°aq/
mMgCl2°aq) or
KPN(Fa)=(
XMe2SiO4/
XFe2SiO4)/(
mMeCl2°aq/
mFeCl2°
aq), vs. ionic radius (PC-IR) diagrams are drawn based on the experimental results. In the case of forsterite, the PC-IR curve has a local maximum near Ni
2+ and shows a concave curve in the region of larger ionic size. However Zn
2+ deviates from such a trend. In the case of fayalite, the PC-IR curve shows a convex curve with a peak near Ni
2+ except for 500°C. Also in this case, Zn
2+ deviates from such a trend. The anomaly of Zn
2+ may be attributable to its tetrahedral site preferency. The
KPN value for Ni
2+ decreases with increasing temperature, whereas those for the other elements except for Ca
2+ increase. The optimum ionic radius for forsterite and fayalite seem to increase slightly with increasing temperature.
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