Since Szilard and Chalmers prepared the carrier-free radiohalogens from the organohologen compouds in 1934, the Szilard-Chalmers method has been applied to the separation of radioisotopes in a high specific activity.
In order to prepare silicon-31 and phosphorus-32 in a high specific activity, the authors investigated the process with tributyl phosphate as the target material.
Tributyl phosphate was bombarded with neutron by the cyclotron (neutron flux: 10
7n/cm
2.sec), and radioactive
31Si and
32P formed were extracted from tributyl phosphate with the various kinds of extracting reagents.
The percentage yield of separated
31Si activity showed the maximum value 87.5% when potassium hydroxide-solution of pH 12.5 was used, while percentage yield of
32P showed the maximum value, 54.3%, in the same conditions.
Both anion and cation exchange resins were tried for the separation of
31Si and
32P from each other, and the cation exchange resin, Diaion SK-1 (ferric form), gave the most preferable results.
31Si and
32P separated by the procedure mentioned above were almost in a carrier-free form, and rediochemical purity of
31Si was 99.9% and that of
32P was nearly 100.0%
Thus, we could prepare the radioactive
31Si and
32P in a high specific activity and in a high radiochemical purity by a simple procedure in a short while.
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