A method is described of preparing Cr foils as thick as 20 to 50mg/cmcm
2, to be used as targets in the production of
52Fe.
The Cr was electroplated from an electrolyte solution (300g/l CrO
3, 2.0g/l H
2SO
4 of s.g., 7.0g/l Na
2SiF
6) on a pure Cu sheet and then the Cu was removed by dissolution in (1:1) HNO
3. Free Cr foil thus obtained was soaked in a 1:1 mixture of 20% NH
4OH and 10% (NH
4)
2S
2O
8 for 30min. After the foil was washed with water, it was heated at 120° to 150°C.
For the electroplating, a cell with Pt anode and Cu sheet cathode was made of Lucite (cell (a)) and of glass (cell (b)), with deposition areas of 2.54cmcm
2 and 7.07cmcm
2, respectively. Direct current (6V) was supplied from a storage battery.
For the preparation of enriched
50Cr targets, the electrolysis conditions were studied in detail. Using cell (a), the electrolysis could be performed without rotating the anode, at 275mA/cmcm
2 with an average current efficiency of-20%, after striking at 2A (787mA/cmcm2) for 40 to 60 sec. After 4 hr a foil of 60mg/cmcm
2 thickness was obtained from 3-5ml of the electrolyte solution with a deposition yield of 32%.
For the preparation of natural Cr target with use of cell (b), the striking was at 3.0 to 2.5A for 40-60 sec, and the electroplating was continued for 90 to 120 min at 250-300mA/cmcm
2 while rotating the anode, resulting in foils of 20-40mg/cmcm
2 thickness and 30mm in diameter.
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