The solidification sequences of multi-component white cast irons containing different types of carbides were investigated by means of thermal analyses and quenching tests. In the case of cast iron with MC and M
2C eutectic carbides, first austenite (
γ) phase or MC carbide precipitates as a primary phase, then the L→
γ+MC eutectic reaction takes place and finally, the solidification finishes by the L→
γ+M
2C eutectic reaction. In cast iron in which MC and M
7C
3 carbides coexist, the solidification begins with the precipitation of the primary
γ phase or MC carbide, followed by the L→
γ+MC eutectic reaction goes, and then the L→
γ+M
7C
3 eutectic reaction. As for cast iron with MC, M
7C
3 and M
2C eutectic carbides, the solidification sequence is as follows : L
0→
γ+MC+(L
1), L
1→
γ+M
7C
3+(L
2) and L
2→
γ+M
2C. EDS analyses of alloy concentrations in the liquid regions of the quenched sample demonstrated the propriety of each eutectic reaction during solidification.
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