The effects of alloying elements on graphite (
TEG) and cementite eutectic temperature (
TEC) of cast iron, and the difference between them (Δ
TE) were investigated. A thermal analysis system consisting of three cups was used to measure eutectic temperature. The order of the expanding effect on Δ
TE is as follows : Si> Al> C
<2.9%> Cu> Co> P> Ni> C
>2.9%. The order of the narrowing effect on Δ
TE is as follows : B> S
>0.44%> V> Cr> S
<0.44%> Mn> Nb> Ti> Sn> W> Mo> Sb. Mn and Ti form sulfide, so that they expand Δ
TE for a low content of element and narrow Δ
TE when the content is less than the transition content. It can be concluded that Δ
TE is not related to carbon activity but to the distribution coefficient of element between cementite and austenite.
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