Four kinds of multi-component white cast irons with different combinations of carbide type were poured into furan molds with different diameters, and cooling curves were taken using a R thermocouple inserted at the center of each mold cavity. The microstructural components in as cast iron, such as γ dendrite arm spacing (
Dp), diameter (
DMC) of MC carbide, lamellar spacing (λ
M2C) of M
2C carbide, area fraction (
Seut) of (γ + M
2C) eutectic or that of both (γ + M
2C) plus ( γ + M
7C
3) eutectics, were well related to each characteristic cooling rate, while the area fraction of MC carbide was little affected by the cooling rate. The relations are expressed by,
DP = 25.1 ⋅
VP-0.36 (
VP : cooling rate during precipitation of primary γ ),
DMC = 4.4⋅
VE-MC-0.18 (
VE-MC : cooling rate during precipitation of ( γ + MC) eutectic), λ
M2C = (1.1∼2.0)⋅
VE-M2C-0.28∼-0.21 (
VE-M2C : cooling rate during precipitation of (γ + M
2C) eutectic,
Seut = (2.0∼15.3)⋅
VA-0.23∼-0.16 (
VA : average cooling rate from start to end of solidification)
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