Proceedings of the Annual Conference of The Japan Institute of Energy
Online ISSN : 2423-8325
Print ISSN : 2423-8317
ISSN-L : 2423-8317
第25回日本エネルギー学会大会
Displaying 101-150 of 155 articles from this issue
  • Nao Kashimura
    Pages 184-185
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    In this study, chromotropic acid-intercalated layered double hydroxides (LDHs) with zinc and aluminum were synthesized and adsorption of Cu2+ to the LDHs was characterized. 1 g of LDHs adsorbed the 750 mg of Cu2+, while 1 g of LDHs in the absence of chromotropic acid adsorbed 610 mg of Cu2+. The result shows chromotropic acid enhanced amount of adsorbed Cu2+. Adsorption isotherm shows that LDHs adsorbed Cu2+ by chemisorption. The amount of the adsorbed Cu2+ increased with time and leveled-off at 240 min.

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  • Keiichi NOSHO, Masao YUKUMOTO, Haruki TANI
    Pages 186-187
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Liquefaction of waste plastic is a one of feedstock recycling technology. Especially, catalytic cracking system with spent FCC catalyst gives higher yield and higher quality oils than thermal degradation process. Granulated blast furnace slag(GBF slag) contains mainly SiO2, Al2O3 and CaO that is similar with zeolite(aluminosilicate) in FCC catalyst. In this study, granulated blast furnace slag was used for catalytic liquefaction as alternative spent FCC catalyst. The granulated blast furnace slag gave higher yield and lower carbon number products than pyrolysis. However, this result is lower than spent FCC catalyst that is given via different mechanism.

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  • Characteristics in grinding test and evaluation for small-sized concrete aggregate
    Shinichi UCHIDA, Yoshihiko HORIE, Akifumi NAKASHITA, Eiichi AKATSU, Yo ...
    Pages 188-189
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Integrated coal Gasification Combined Cycle (IGCC) has higher efficiency and lower environmental impact, because of consisting of tremendous advanced gasification technology and gas turbine technology. In IGCC the ash in coal is molten and transformed to glassy slag instead of fly ash. The harmless slag is expected to be used in concrete manufacturing or basement of asphalt paving. In order to get JIS certification of slag, several evaluation tests including shape arrangement by grinding, measurement of size distribution, physical property, chemical analysis and chemical leaching test, have been performed and resulted.

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  • Daisuke EBISUI, Kazuyuki KISIDA, Yuji YAMADA, Takashi MASUMOTO
    Pages 190-191
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Medical wastes discharged from a medical institution are varied such as paper diapers with high water content or plastics with high calorific value. Therefore, it is generally agreed today that it is difficult to incinerate medical wastes completely and stably without another waste and/or auxiliary fuel. Vertical combustor that can incinerate various wastes without another waste and auxiliary fuel has developed and delivered to Tokyo Waterfront Recycle Power in 2007 for medical wastes. Currently, 4.15 MPa saturated steam is efficiently recovered.

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  • Katsutoshi SATO, Katsutoshi NAGAOKA
    Pages 248-249
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    We demonstrated the cold-start process for oxidative reforming (OR) of n-butane. In this process, without heating the catalyst by external energy OR is triggered rapidly and repeatedly over reduced CeO2 supported Rh catalysts from ambient temperature. Redox property of oxide support, i.e. spontaneous oxidation of the reduced catalyst support, CeO2-x to CeO2, and in-situ reduction of the catalyst support during OR, CeO2 to CeO2-x, are found to be key factors for construction of this process.

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  • Tamiro KANABE
    Pages 250-251
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    It has been demonstrated by the experiment that aqueous solution particles of potassium carbonate functioned as a liquid catalyst for hydrogen production and as a CO2 absorber. It has become clear that hydrogen was produced by the reaction of steam with coke(C) generated to inner wall face of the reactor by coking. As to the experiment, the 200ml normal temperature aqueous solution of potassium carbonate was put into the reactor. Both of inlet valve and outlet valve of the reactor were shut. Temperature and total pressure of steam and some gases in the reactor were measured with the elapsed time. The reactor was heated by its outer electric heater. As a result, saturated liquid water changed to wet steam, saturated steam and superheated steam as time proceeded. And five reactions occurred in the reactor.

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  • Xiumin Li, Abuliti Abudula, Guoqing Guan
    Pages 252-253
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    An in-situ intercalation method was demonstrated in this work to expand the interlayer spacing of electrodeposited NiFe Layered double hydroxides (LDH) electrodes. Compared with traditional intercalation/exfoliation and coating approach, better interface connection and stability of electrodeposited LDH electrodes were maintained in this way. Experimental results showed that the inter-layer distance of NiFe LDH material was increased from 7.8 Å to 9.1 Å by immersing NiFe LDH electrode in formamide at 80 °C for 3 h. Electrochemical water electrolysis results indicated low overpotentials of 237 and 408 mV were required to sustain 10 and 100 mA cm-2 current densities for oxygen evolution reaction. In addition, with the assistance of ultrasound, the required time of intercalation process was reduced drastically and a lower overpotential was exposed.

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  • Yuichi MANAKA, Masayuki IGUCHI, Naoya ONISHI, Hajime KAWANAMI, Yuichir ...
    Pages 254-255
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    The hydrogen storage system using an interconversion cycle between formic acid and CO2 has received much attention today. Recently, we have developed iridium-bipyridine based catalysts for dehydrogenation of formic acid and hydrogenation of CO2. Here, we report about a new catalyst design, which is containing a diazole moiety on the ligand, for dehydrogenation of formic acid toward a practical application.

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  • Satoshi HORIKOSHI, Momoko KAMATA
    Pages 256-257
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Continuous hydrogen evolution occurred in near-quantitative yields from the dehydrogenation of an organic hydride (methylcyclohexane; MCH) through a microwave-assisted catalyzed process taking place in a fixed-bed reactor in the presence of Pd catalyst particles supported on activated carbon particulates (Pd/AC). Unlike conventional heating, the microwave heating method displayed a large temperature distribution experimentally observed along the vertical catalyst fixed-bed reactor attributed to the distribution of the microwave electric field, among other factors. A principal feature of the microwave-assisted method was the rapid heating response of the catalyst at low microwave power with considerable energy saving relative to conventional heating with a ceramics heater (2 min versus ca. 35‒40 min; 27W versus 139 W). A more uniform distribution of the microwave-generated heat and introduction of warmer liquid organic hydride (greater than ambient) should lead to significant improvement in process efficiency.

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  • Hiroki UESATO, Hiroki MIYAOKA, Takayuki ICHIKAWA, Yoshitsugu KOJIMA, T ...
    Pages 258-259
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Ammonia borane (AB) can be regenerated by using hydrazine and liquid ammonia via intermediate phases of N2H4BH3 and B(NH2)3. By an analogy of this method, we have recently reported that AB forms from hexagonal boron nitride (h-BN) by milling under hydrogen pressure and then using hydrazine and ammonia. However, this regeneration mechanism is still unclear. In this work, the reaction pathways of hydrogenated h-BN and B samples with liquid hydrazine-ammonia solution have been investigated in order to understand the key factor for forming AB by using hydrazine and ammonia. As a result, the reaction pathway for the hydrogenated h-BN is similar to that for polyborazirene (PB) since the same intermediates were observed after both the reactions with hydrazine and ammonia. On the other hand, the hydrogenated B was not converted to AB by using hydrazine and ammonia, indicating that existence of N-B-H bonding is necessary to obtain AB by using hydrazine and ammonia.

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  • Keita SHINZATO, Yuki NAKAGAWA, Shigehito ISOBE, Tessui NAKAGAWA, Keita ...
    Pages 260-261
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Ammonia borane (AB: NH3BH3) is a promising solid state hydrogen storage material because it contains >19 mass% of hydrogen. However, the thermal decomposition of AB kinetically requires high temperature, and considerable amount of harmful by-product gases emit from AB. Recently, the decomposition properties of AB have been improved by the composite with alanates (MAlH4, M = Na, Li). It was reported that the new compound NaAl(NH2BH3)4 formed during mechanical milling of 4AB-NaAlH4. In this work, we have tried to synthesize NaAl(NH<sub>2</sub>BH<sub>3</sub>)<sub>4</sub> in THF solvent (Solution method) to obtain the single phase with high-purity. The powder X-ray diffraction pattern of the product obtained by the solution method was similar to that obtained by the solid method, suggesting that NaAl(NH2BH3)4 can be synthesized by the solution method as well. However, the 23Na-nuclear magnetic resonance (NMR) spectrum suggests that a different phases from NaAl(NH2BH3)4 coexist. Thus, in order to obtain the single phase of NaAl(NH2BH3)4, further optimization of reaction conditions would be necessary.

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  • Tetsuo UMEGAKI, Ryota ENOMOTO, Yoshiyuki KOJIMA
    Pages 262-263
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Ammonia borane (NH3BH3) is able to hydrolyze at room temperature to generate hydrogen with high purity. For this feature, ammonia borane is expected as a hydrogen storage material for polymer membrane fuel cells for mobile use. It is reported that metal-based catalysts show high active for this reaction. Their catalytic activity was influenced by the morphology of their active species. In order to investigate the influence of the morphology, we have focused on spherical particle materials with hollow void because of their easily controllable homogeneity. In our researches, we have found that hollow nickel-silica composite spheres were fabricated from the spherical composite particles by in-situ activation of the particles with small amount of sodium borohydride during hydrolysis of ammonia borane, and the hollow spheres show high activity for the hydrogen generation from aqueous ammonia borane solution. In this study, we fabricated the highly active in-situ synthesized hollow ruthenium-silica composite spheres using the same method and investigate the effects of the preparation conditions on their catalytic activity for hydrolytic dehydrogenation of ammonia borane.

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  • Hironori KAWAI, Koji KAWAHITO, Hiroki MIYAOKA, Liang ZENG, Yoshitsugu ...
    Pages 264-265
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Recently, metal hydrides have been studied as conversion-type negative electrode materials for lithium-ion battery. Magnesium hydride (MgH2) known as hydrogen storage materials is one of promising electrode materials because of the high theoretical capacity, which is 2036 mAh/g and five times larger than that of conventional graphite electrode. During the reaction with Li ions, MgH2 is converted to Mg and LiH. On the analogy on MgH2, it is expected that other hydrides also work as electrode materials. However, there are few reports about other hydrides currently. In this work, the electrochemical properties of metal hydrides, such as MgH2, TiH2, CaH2 and VHx, are systematically investigated. From the experimental results, the correlation between thermodynamic and electrochemical properties is clearly found except for CaH2. In the case of CaH2, an unexpected side reaction possibly proceeds.

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  • Keita NAKAJIMA, Taihei AOKI, Hikaru MIYAOKA, Hiroki MIYAOKA, Takayuki ...
    Pages 266-267
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Sodium borohydride (NaBH4) absorbed 2 mol of ammonia (NH3) /1 mol of NaBH4 and the equilibrium pressure was appeared at 0.09 MPa and 20 °C. The gravimetric NH3 density was 47 wt% and the vapor pressure was about 1/10 lower than that of liquid NH3. When NaBH4 absorbed more than 2 mol of NH3, the NaBH4-NH3 system is changed to a solution state, and then the ammonia vapor pressure linearly increases with the NH3 concentration. In this work, the solution properties are analyzed and discussed from the NH3 absorption properties obtained by experiments.

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  • Yoshitsugu KOJIMA, Tomoyuki ICHIKAWA, Hiroki MIYAOKA, Takayuki ICHIKAW ...
    Pages 268-269
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Hydrogen is a CO2 free fuel and can be stored in many different forms as compressed or liquefied hydrogen in tanks. Liquid ammonia has been expected as a hydrogen carrier because it has a high H2 storage capacity with 17.8 wt% and 10.7 kgH2/100L at 1MPa and 298K. The volumetric hydrogen density is about 1.5 times of liquid hydrogen, and it is easily liquefied under about 1 MPa at room temperature. Current PEM fuel cells are poisoned even by trace levels (~1 ppm) of ammonia. The catalyst such as Ru supported on MgO shows the ammonia conversion of 99.8 % at 773K, which corresponds to ammonia concentration of 1000 ppm. After hydrogen and nitrogen generation by ammonia cracking, ammonium hydrogen sulfate (NH4HSO4) can be utilized to decrease the ammonia concentration from 1000 ppm to 0.1 ppm.

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  • Yusuke ONO, Takahide HANEDA, Atsushi AKISAWA
    Pages 270-271
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Although fuel cell vehicles (FCV) have attracted the attention, the hydrogen stations are not sufficient. This study focuses on ”Residential Fuel Cell System” to produce hydrogen for FCVs. It is because the gas-reformers have capability to produce hydrogen while the fuel cells do not operate during nighttime. An optimization model was employed to estimate the possible amount of hydrogen supply by one residential fuel cell. The result indicates that one fuel cell can satisfy the hydrogen demand for transportation of 8000km.

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  • Takashi YANAGIDA, Hirofumi KUBOYAMA, Makoto KIGUCHI, Hirotaka KOMATA
    Pages 272-273
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    A shortage of the unused biomass fuel in FIT certified woody biomass power generation in some parts of the Kyushu have the potential to cover by bamboo fuel. However the collection cost of bamboo is high, it is economically difficult to use bamboo fuel in wood biomass power generation at present.

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  • Tomoko OGI, Masakazu Nakanishi, Yoshio FUKUDA
    Pages 274-275
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Herbaceous biomass is a promising candidate of gasification feedstock, but still unused and wasted because it is too fibrous to be stably supplied, which easily winds around a feeder, and its amounts is not eonough to be gasified alone. In this paper, we proposed a thermal treatment for mixture of herbaceous biomass (Ryegrass) powder and woody (cedar wood) chips at low temperature in order to reduce their volume, to lump them together and, consequently, to stably supply then to an advanced entrained-flow type gasifier, to which feedstock of 5mm or larger was applicable. The advanced entrained-flow type gasification was developed for reducing pulverizing energy because feedstock should be pulverized to powder before applied to a usual one. When gasifying the lumping sample, which we named ”coating sample”, in the laboratory-developed entrained-flow gasifier, gasification proceeded well and gas of suitable compositions for BTL synthesis was obtained.

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  • Masakazu NAKANISHI, Takahisa TSUGOSHI, Tomoko OGI
    Pages 276-277
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Japanese cedar wood (Cryptomeria japonica) was thermogravimetrically analyzed, atmosphere of which was helium, and produced compounds were mass-spectrometrically analyzed for studying its pyrolysis process. A specially designed skimmer interface was used for connecting the thermogravimetric analyzer and the mass-spectrometer (TG/MS). Phenol derivatives and oxygenated compounds were respectively produced from lignin and holo-cellulose. The TG/MS analyses showed that the heavier compounds in each group had the narrower thermal peaks. For example, propylguaiacol had one peak and 2-methylphenol had two peaks, weights of which were respectively 166amu and 108amu. Their temperature dependences suggested that lignin thermally decomposed to phenol derivatives of various molecular weights and that heavier ones successively decomposed to lighter ones.

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  • Kiyoshi SAKURAGI, Miki KOKUBO, Chiaki HORI, Takuya ISHIDA, Kiyohiko IG ...
    Pages 278-279
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    We performed a comparative analysis of the expression levels of proteins secreted by Phanerochaete chrysosporium cultured with either untreated or ammonia-treated lignocellulosic biomass. In the culture with ammonia-treated biomass, the relative production of a xylanase belonging to the glycoside hydrolase (GH) family 11 increased significantly, while that of acetyl xylan esterases, belonging to carbohydrate esterase family 1, decreased. During the enzymatic saccharificaion of the ammonia-treated biomass, the addition of a xylanase (belonging to GH family 11) to the culture with non-treated birch wood meal significantly increased saccharification yield. These results indicated that P. chrysosporium produced enzymes related to degradation of the de-acetylated xylan-containing biomass. Therefore, enzymes with potential applications in biofuel production, such as xylanase belonging to GH family 11, could be selected from the sequenced genome of P. chrysosporium. Importantly, utilization of these data to assist in the selection of enzyme cocktails for effective degradation of lignocellulosic biomass might contribute to the development and production of biofuels.

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  • Kaede TEJIMA, Masao YUKUMOTO
    Pages 280-281
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Used cooking oil is collected from citizens in Kasugai City,Aichi Prefecture.This oil is converted into Bio-diesel Fuel(BDF),and that is used for fuel of a garbage truck.However,the collected oil in Kasugai City is less than consumed amount of BDF.In this study,possibility of increasing recovery amount is considered by comparing Kasugai City and Kyoto City which is popular with using BDF. Then to grasp the collection situation, a questionnaire survey is performed for citizens.We used Geographic Information System (GIS) for questionnaire results,present condition of recovery amount are mapping.Therefore,most of citizen doesn’t know about collecting used cooking oil and most of person who brought used cooking oil is over 60.So, we proposed future policy for increasing recovery amount of used cooking oil.

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  • Tetsuto NAKASHIMA, Ryo NANAE, Ryohei WADA
    Pages 282-283
    Published: August 02, 2016
    Released on J-STAGE: March 01, 2017
    CONFERENCE PROCEEDINGS FREE ACCESS

    Ethylene gas was produced by thermal decomposition of cherry’s fallen leaves. Cherry’s fallen leaves was put in large test tube and it was heated by infrared heater, and was raising each 50 °C for 30 minutes and it was heated even 500 °C. Gas was generated much so at high temperature. When natural zeolite was added in the state which melted by zinc chloride and tin (II) chloride, the generated gas was increased at low temperature compared with the case only fallen leaves. It was thought that hydrogen band of cellulose could be cut with zinc chloride and tin (II) chloride and the reaction of zeolite with fallen leaves became easy.

    Lignin reagent was put in regular size test tube, was heated by electric furnace at 500 °C and the generated ethylene gas was measured by gas chromatography. When natural zeolite was added in the state which melted by zinc chloride, the generated ethylene gas was increased.

    Key Words Ethylene gas, Thermal decomposition, Lignin, Fallen leaves, Zeolite, Zinc chloride

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