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Hideki HIRAYAMA, Tohru YATABE, Norimichi NOGUCHI, Norihiko KAMATA
2008 Volume 32 Issue 2 Pages
79-82
Published: 2008
Released on J-STAGE: January 09, 2009
JOURNAL
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We demonstrated AlGaN multi-quantum well (MQW) deep ultraviolet (UV) light-emitting diodes (LEDs) with wavelength in the range of 227-261 nm fabricated on high-quality AlN buffers on sapphire substrates. We achieved crack-free, thick AlN buffer on sapphire with low threading dislocation density (TDD) and atomically flat surface by introducing an ammonia (NH
3) pulse-flow multi-layer (ML) growth method through metal-organic chemical vapor deposition (MOCVD). The edge- and screw-type dislocation densities of AlGaN layer on AlN buffer were reduced to 7.5×10
8 and 3.8×10
7 cm
-2, respectively, by using a ML-AlN buffer. We achieved single-peaked high-brightness operations of AlGaN deep-UV LEDs by fabricating them on the ML-AlN buffers on sapphire substrates. The maximum output power and external quantum efficiency (EQE) of the 261 nm and 227.5 nm LEDs were 1.65 mW and 0.23% under room-temperature (RT) CW operation, and 0.15 mW and 0.2%, under RT pulsed operation, respectively.
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Sachie FUJIKAWA, Takayoshi TAKANO, Yukihiro KONDO, Hideki HIRAYAMA
2008 Volume 32 Issue 2 Pages
83-87
Published: 2008
Released on J-STAGE: January 09, 2009
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High output power 340 nm-band InAlGaN-based multi-quantum-well (MQW) ultraviolet (UV) light-emitting diodes (LEDs) were achieved by using p-type InAlGaN layers. The output power of a UV-LED with p-type InAlGaN layers was approximately 4.7 times larger than that achieved with p-type AlGaN layers. We obtained an output power of 8.4mW from a 346 nm InAlGaN-QW LED by optimizing the band line-up to suppress electron overflow and by reducing the threading dislocation density (TDD) of the AlN/AlGaN template.
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Tamotsu OKAMOTO, Kunio TAKAHASHI, Hiroshi OHSAWA, Ken-ichi FUKUCHI, Ko ...
2008 Volume 32 Issue 2 Pages
88-92
Published: 2008
Released on J-STAGE: January 09, 2009
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We attempted the development of highly efficient fishing lights using LEDs for saury fishing. Considering the spectral luminous efficacy characteristic of a Pacific saury, LED fishing lights were fabricated. Transmission properties in sea water in LED fishing lights were investigated, and it was found that the fabricated LED fishing lights sufficiently can be utilized even in sea water. Furthermore, we attempted the saury-fishing experiments by using the LED fishing lights, and comparable catch of Pacific saury was achieved by approximately 55% electric power by using both LED poles and incandescent lamp poles.
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Takayuki NAKANISHI, Setsuhisa TANABE
2008 Volume 32 Issue 2 Pages
93-96
Published: 2008
Released on J-STAGE: January 09, 2009
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Eu
2+-doped BaSi
2O
5 glasses were prepared by melting method and the glass-ceramics (GCs) were obtained by heat-treatment at various temperatures between 800 °C and 1000 °C. The single phase of BaSi
2O
5 micro-crystal precipitated in the GCs by heat-treatment above 950 °C, and the quantum yield (QY) of Eu
2+ fluorescence became higher than that of other GCs, in which other crystal phases precipitated. When the BaSi
2O
5 precipitated, the QY increased drastically.
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Noriharu MIYAHO, Noriko KONNO, Takamasa SHIMADA
2008 Volume 32 Issue 2 Pages
97-102
Published: 2008
Released on J-STAGE: January 09, 2009
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In this paper we evaluated the effects of 1/f fluctuation of Green LED light emitted from the specific object by using psychological and physiological experimental tests of spectral electroencephalogram (EEG) topography. In addition, we also verified that the combination of appropriate aroma, blue LED light irradiation and music such as “Mozart: Serenade in Eine Kleine Nacht Musik” has improved mental healing conditions. We confirmed the possibility that the effect of “Healing” would be improved by the above mentioned environments.
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Mamoru KITAURA, Yohei INADA, Kazutoshi FUKUI
2008 Volume 32 Issue 2 Pages
103-106
Published: 2008
Released on J-STAGE: January 09, 2009
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The phosphor of ScPO
4:Zr
4+,Mn
2+ has been synthesized in order to increase the photoluminescence (PL) intensity of the blue-green (BG) band at 2.52 eV in YPO
4:Zr
4+,Mn
2+ phosphor. PL properties of this material have been investigated. A PL band is predominantly observed at 2.34 eV in ScPO
4:Zr
4+,Mn
2+. This green (G) band is most likely caused by the intra-3d transition of the Mn
2+ ion occupying a Sc
3+ site, in analogy with PL properties of the BG band. The G band surpasses the BG band in PL intensity. Discussions are conducted on the change of PL properties in ScPO
4:Zr
4+,Mn
2+ phosphor.
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Hitoshi SATO, Hirohiko HIRASAWA, Hirokuni ASAMIZU, Natalie FELLOWS, An ...
2008 Volume 32 Issue 2 Pages
107-110
Published: 2008
Released on J-STAGE: January 09, 2009
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We demonstrate high power blue and green InGaN/GaN multiple-quantum-well (MQW) light emitting diodes (LEDs) grown on low extended defect density semipolar (10 1 1) and (11 2 2) bulk GaN substrates by metal organic chemical vapor deposition. The output power and external quantum efficiency (EQE) at 20 mA under pulsed operation (10 % duty cycle) were 19.7 mW and 34.4 % for the blue LED and 9.0 mW and 18.9 % for the green LED, respectively. The blue LED showed <1 nm red-shift with change in drive current from 1 - 200 mA, indicating a significant reduction of polarization related internal electric fields.
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Natalie FELLOWS, Hisashi MASUl, Frederic DIANA, Steven P. DENBAARS, Sh ...
2008 Volume 32 Issue 2 Pages
111-114
Published: 2008
Released on J-STAGE: January 09, 2009
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We have demonstrated the ability to increase the luminous flux and luminous efficacy of white light-emitting diodes (LEDs) by randomly patterning the surface of the yellow phosphor matrix. The phosphor was moved away from the LED die by placing it on top of a silicone optic and then roughening the surface of the phosphor/resin mixture. It was found that the roughening increases the luminous flux and efficacy by 10% over the smooth, non-patterned phosphor mixture. The roughened sample’s operating voltage, luminous flux, luminous efficacy, CCT, color coordinates, and CRI were 3.2 V, 7.4 lm, 115.6 lm/W, 4244 K, (0.388, 0.448), and 61 at 20 mA, CW, and room temperature operation. A brief presentation on phosphor scattering is introduced to help explain the effect of the roughening.
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Yitin ZHU, Nadarajah NARENDRAN
2008 Volume 32 Issue 2 Pages
115-119
Published: 2008
Released on J-STAGE: January 09, 2009
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The accuracy of results from Monte Carlo ray-tracing analysis significantly depends on the input values of the optical properties of the various package components. One important piece of input information is the phosphor particle MFP (mean-free-path), which is not easily determined. This study introduced a method to determine the MFP by matching the experimental results with optical ray-tracing analysis at a wavelength beyond the phosphor excitation range. Using these experiment values for MFP in an optical ray-tracing analysis of a white LED package showed an excellent match with measured results for light output and chromaticity.
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Yasuhiro SEKIMOTO, Hirotake KAJII, Yutaka OHMORI
2008 Volume 32 Issue 2 Pages
120-123
Published: 2008
Released on J-STAGE: January 09, 2009
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First, we investigated the transient characteristics of poly(9,9-dioctylfluorene)(PFO)-based polymer OLEDs (PLEDs) doped with green emissive phosphor
fac-tris(2-phenylpyridine)iridium(III) [Ir(ppy)
3] and red emissive phosphor tris(1-phenylisoquinoline)iridium(III) [Ir(piq)
3] by applying the voltage pulse on the devices, and achieved the maximum luminance of 4800 cd/m
2 and the ideal white emission with the Commission Internationale de L’Eclairage (CIE) coordinates of (0.33, 0.35) at the pulse width and frequency of 100 ns and 1 kHz, respectively. Especially, the CIE coordinates can be tuned from (0.25, 0.29) to (0.51, 0.40) by varying pulse width and frequency. Second, we investigated white OLEDs with blue emissive phosphor bis[(4,6-difluorophenyl)-pyridinato-
N,
C2] (picolinate)iridium(III) (FIrpic) and some red emissive materials. Using FIrpic and red emissive rare earth complex of tris(divenzoylmethane)-mono(4,7-dimethylphenanthroline) europium(III) [Eu(dbm)
3phen] doped in poly(
N-vinyl-carbazole) (PVK), the white emission of (0.31, 0.38) in the CIE coordinates was obtained at a current density of 0.5 mA/cm
2. Utilizing the different transient characteristics between the host and dopant, emission color has been successfully tuned by varying the applied pulse width and frequency.
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Toshimitsu KANEKO, Kazuhiko HORINO, Hiroshi YAMAMOTO, Hiroaki ITO, Aki ...
2008 Volume 32 Issue 2 Pages
124-128
Published: 2008
Released on J-STAGE: January 09, 2009
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The fabrication of InGaN/GaN light emitting diodes with reverse-tapered microholes (RH-LEDs) and their optical —electrical properties were demonstrated. A high light extraction efficiency was realized with the RH-LEDs owing to the diffraction of light and effective extraction of photons caused by the microholes. The estimated light extraction efficiency of the RH-LEDs was as high as 85%; this is 1.5 times higher than that of conventional LEDs having no microholes. The theoretical results were highly consistent with the experimental results.
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Y.Q. LI, H.T. HINTZEN
2008 Volume 32 Issue 2 Pages
129-134
Published: 2008
Released on J-STAGE: January 09, 2009
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In this overview paper, novel rare-earth doped silicon nitride based phosphors for white LEDs applications have been demonstrated. The luminescence properties of orange-red-emitting phosphors (M
2Si
5N
8:Eu
2+) and green-to-yellow emitting phosphors (MSi
2N
2O
2:Eu
2+, M = Ca, Sr, Ba) are discussed in detail with a focus on the relationship between the properties and structures. With high conversion efficiency in the near UV/blue region, along with high chemical/physical stability, Eu
2+ - and Ce
3+ - activated alkaline-earth silicon nitride and oxynitride materials are excellent wavelength-conversion phosphors for white LEDs.
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Kazuaki TSUJI, Koutoku OHMI
2008 Volume 32 Issue 2 Pages
135-138
Published: 2008
Released on J-STAGE: January 09, 2009
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A novel red phosphor of CuAlS
2:Mn for white LEDs has been successfully prepared by solid-state-reaction method using an opened-tubular-furnace. It has been found that both photoluminescence (PL) intensity and thermal stability are improved by Si-codoping. The currently obtained PL stimulus value Y under 380-nm-excitation is about 67 % compared to La
2O
2S:Eu. The PL intensity at 100°C maintains 95 % of that at a room temperature.
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Tsuyoshi OHASHI, Koutoku OHMI
2008 Volume 32 Issue 2 Pages
139-142
Published: 2008
Released on J-STAGE: January 09, 2009
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Ba
2SiS
4:Ce has been proposed as a novel blue phosphor for white LED application. It has been found that photoluminescent characteristics are improved by Al-codoping, which realizes a high doping of Ce
3+ luminescent centers. The relative PL luminance of 145% has been achieved compared to the commercial BAM under 405-nm-excitation. The internal quantum efficiency is about 36 %. The PL intensity at 150°C maintains about 80% of that at room temperature. It has been also confirmed that Ba
2SiS
4:Ce is chemically stable enough for applying to white LEDs.
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Nola LI, Shen-Jie WANG, Eun-Hyun PARK, Zhe Chuan FENG, Hung-Lin TSAI, ...
2008 Volume 32 Issue 2 Pages
143-147
Published: 2008
Released on J-STAGE: January 09, 2009
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MOCVD growth of InGaN on ZnO substrates has achieved indium concentration as high as 43% as observed by high-resolution X-ray diffraction (HRXRD). The uniqueness of this finding is the absence of phase separation and the higher indium incorporation compared to growth on thick GaN/sapphire. Transmission electron microscopy (TEM) shows perfectly matched GaN and ZnO lattices. In addition, atomic layer deposition (ALD) transition layers have been grown in order to provide a transition layer on ZnO substrates to block Zn diffusion and allow for future substrate removal for thin nitride fabrication.
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Bin-Juine HUANG, Huan-Hsiang HUANG, Chun-Wei CHEN, Min-Sheng WU
2008 Volume 32 Issue 2 Pages
148-155
Published: 2008
Released on J-STAGE: January 09, 2009
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High-power LED should reject about 6 times of heat of the conventional lighting device and keep the LED junction temperature below 80°C to assure reliability and low light decay. In addition, no fan is allowed and the heat dissipation design should not interfere with the industrial design of lighting fixture and have a light weight. This thus creates an extreme thermal management problem. The present study has shown that, using a special heat dissipation technology (loop heat pipe), the high-power LED lighting luminaire with input power from 36 to 150W for outdoor and indoor applications can be achieved with light weight, among 0.96 to 1.57 kg per 1,000 lumen of net luminous flux output from the luminaire. The loop heat pipe uses a flexible connecting pipe as the condenser which can be wounded around the reflector of the luminaire to dissipate the heat to the ambient air by natural convection. For roadway or street lighting application, the present study shows that a better optical design of LED lamps can further result in power consumption reduction, based on the same illumination on road surface. The high-power LED luminaries developed in the present study have shown that the energy saving is > 50% in road lighting applications as compared to sodium light or > 70% compared to mercury light.
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Paul MILLER, Teresa GOODMAN
2008 Volume 32 Issue 2 Pages
156-160
Published: 2008
Released on J-STAGE: January 09, 2009
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The use of light emitting diodes (LEDs) is expanding rapidly, in areas ranging from lighting, signalling and escape route indication to medical diagnosis and treatment. For all these applications, knowledge of the spectral and spatial characteristics of the devices is essential. In addition, recent significant advances in the brightness of LEDs and the introduction of devices emitting at shorter wavelengths has led to increasing concern regarding the safety of LED products.
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Masafumi JINNO, Keiji MORITA, Yudai TOMITA, Yukinobu TODA, Hideki MOTO ...
2008 Volume 32 Issue 2 Pages
161-169
Published: 2008
Released on J-STAGE: January 09, 2009
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By using Blue, Green and Red LEDs it is shown that the Broca-Sulzer effect holds for a continuous pulse operated LED lighting system. The effective enhancement at 5% duty ratio and frequency of 60 Hz is between 1.01 to 2.22 times that of DC operation although this is not as high as it is in the single pulse discharge lamp case. However, this result shows that there is a possibility of improving the efficiency of an LED and a PWM circuit for pulsed operation for developing a highly efficient lighting system.
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Energy Saving Lighting and Illumination by Using Repetitive Intense and Fast Pulsed Light Sources and the Effect on Human Eyes
Masafumi JINNO, Keiji MORITA, Yudai TOMITA, Yukinobu TODA, Hideki MOTO ...
2008 Volume 32 Issue 2 Pages
170-176
Published: 2008
Released on J-STAGE: January 09, 2009
JOURNAL
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By using Blue, Green and Red LEDs it is shown that the Broca-Sulzer effect holds for a repetitive pulse operated LED lighting system. In other words Talbot-Plateau Law does not hold. The effective enhancement at 60 Hz with a 5% duty ratio is about 1.5 to 2.7 times that of DC operation for blue and green light. This result suggests that pulsed operation can be a way to solving the energy saving problem of lighting.
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Kazumasa HIRAMATSU, Hideto MIYAKE, Da-Bing LI
2008 Volume 32 Issue 2 Pages
177-182
Published: 2008
Released on J-STAGE: January 09, 2009
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In this paper, the high quality AlGaN with high-Al content was grown on in-situ monitoring controlled selective area growth (SAG) GaN and the dislocation density of AlGaN is 1-3×10
8 cm
-2. Furthermore, we use SAG to fabricate InGaN/GaN pyramid structures. CL (Cathodoluminescence) measurements reveal that the thickness, CL peak wavelength and CL intensity gradually increased from the bottom to the top of the facet. Furthermore, Vacuum fluorescent display (VFD) based on InGaN/GaN pyramid structures was demonstrated.
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Hung-Yu CHOU, Tsung-Hsun YANG
2008 Volume 32 Issue 2 Pages
183-186
Published: 2008
Released on J-STAGE: January 09, 2009
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In this work, an empirical model for the emission spectra of LEDs is proposed to describe some crucial optical properties of LEDs. As well known, the junction temperature and the electric driving current are two most important factors of all. According to the phenomenal observation, the empirical model for the emission spectra of LEDs is established to simultaneously include the effects from both the junction temperature and the electric driving current. As a result, the empirical model can be applied for the prediction of the chromatic shifts due to the drift of the operating junction temperature. In addition, the stabilization of the chromatic characteristics is obvious.
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Wang Nang WANG, C. LIU, A. GOTT, S. DENCHITCHAROEN, P. SHIELDS, L. MES ...
2008 Volume 32 Issue 2 Pages
187-190
Published: 2008
Released on J-STAGE: January 09, 2009
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This paper presents the results using an alternative defects and strain minimizing technique with nanostructures as the compliant layer to grow III-V nitrides onto foreign substrates. Defects reduction and stress relaxation had been observed through HRTEM on GaN grown on sapphire and silicon. Results of LED devices on silicon with performance compatible with those on sapphire are presented.
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Yoichi YAMADA, Kazuto IWAMURA, Takahiro KURONAKA, Naohiko SHINOMURA, T ...
2008 Volume 32 Issue 2 Pages
191-195
Published: 2008
Released on J-STAGE: January 09, 2009
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The internal quantum efficiency (IQE) of InGaN-based light-emitting diodes has been studied by means of excitation-power-density- and temperature-dependent photoluminescence spectroscopy. The IQE was evaluated at various excitation photon energies using a wavelength-tunable dye laser system. The IQE obtained under selective excitation of InGaN active layers was higher than that obtained under band-to-band excitation of GaN and AlGaN cladding layers. The enhanced value of IQE under selective excitation reflected the intrinsic optical quality of the InGaN active layer itself.
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Masaru SUGIMOTO, Yoji URANO, Ikko KUZUHARA, Takao HAYASHI, Mikiko MASU ...
2008 Volume 32 Issue 2 Pages
196-201
Published: 2008
Released on J-STAGE: January 09, 2009
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The encapsulation optical component shaped in an elliptical dome over the LED chip and the mixing of multiple types of fluorescent materials in an appropriate ratio improves colour rendering properties and distribution controllability while suppressing colour variation. The developed technologies can be applied to produce an LED luminaire that resembles a compact ceiling-light but can be used as a downlight with the light intensity equivalent to a 60W incandescent lamp and light quality comparable to a fluorescent lamp.
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Naoto KIJIMA, Yasuo SHIMOMURA, Tomoyuki KURUSHIMA, Hiromu WATANABE, Sa ...
2008 Volume 32 Issue 2 Pages
202-207
Published: 2008
Released on J-STAGE: January 09, 2009
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High-luminous green phosphors and a red phosphor have been newly developed for white LEDs. The developed green phosphors are Ca
3(Sc,Mg)
2Si
3O
12:Ce made by replacing with Mg a part of Sc of green phosphor Ca
3Sc
2Si
3O
12:Ce, a new green phosphor CaSc
2O
4:Ce, and a new host material doped with a rare-earth element, Ba
3Si
6O
12N
12:Eu. The new red phosphor is (Sr,Ca)AlSiN
3:Eu made by replacing a part of Ca of CaAlSiN
3:Eu with Sr.
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