Methane hydrate (MH) is expected as a new resource of natural gases. However MH is solid and it doesn’t flow, thus dissociation methods of MH into water and CH
4 gas in oceanic sedimentary layers are proposed. Here we focused on the exothermic reaction of CO
2 hydrate formation for thermal stimulation of the layers. The possibility for raising temperature of the sedimentary layers by the exothermic heat of CO
2 hydrate is considered by following items. 1) A laboratory experiment to measure temperature through CO
2 hydrate formation in a pressure cell. 2) Proposing a numerical temperature-raising model by CO
2 hydrate formation. 3) An estimation of the temperature raising model using unsteady heat diffusion analysis by simulating the results of the laboratory experiment. 3) An analysis considering the boundary condition of sedimentary layers and the estimated model. As a result, the temperature of the layers can be raised by about 9°C using CO
2 hydrate formation. Then this shows a possibility to use CO
2 as a warming material for oceanic sedimentary layers to exploit MH.
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