The electrolytic deposition behavior of Mo in molten salt has been studied using the equimolar NaCl-KCl molten salt, which contains Li
2MoO
4 as a molybdenum source. In the equimolar NaCl-KCl molten salt containing only Li
2MoO
4, a high cathodic current corresponding to the reduction reaction of Li
2MoO
4 was observed under cathodic polarization. Under this polarization, the deposition of Mo could not be observed, but the deposition of Li
2Mo
2O
5 which grew perpendicular to the substrate surface was observed. On the other hand, in the equimolar NaCl-KCl molten salt containing B
2O
3, AlF
3 or K
2SiF
6 as the second addition agents in addition to the Li
2MoO
4, a higher cathodic current was observed under cathodic polarization, showing that the cathodic reaction was more active. Under the cathodic polarization in the molten salt containing B
2O
3 or AlF
3 as the second addition agent, the deposition of MoO
2 occurred without depending on the polarization potential. On the contrary, under the cathodic polarization in the molten salt containing K
2SiF
6 as the second addition agent the deposition material was changed with the polarization potential. Thus, in the molten salt containing K
2SiF
6, MoO
2 was deposited at high potentials, while Mo was deposited at low potentials. Consequently, it was found that in the equimolar NaCl-KCl molten salt containing Li
2MoO
4 and K
2SiF
6, Mo was deposited under the cathodic polarization at low potential.
抄録全体を表示