The Adsorption of water vapour on glass surfaces in vacuum has been studied. By measuring the time lag in setting up the steady state of molecular flows, one may measure the adsorption of water vapour without the influence of ion gauge.
Using high vacuum techiciques, it is possile to make the experiments with a residual gas of about 1×10
-8mm Hg, and the speed of cleen-up in Fogel type ion gauge for air is obtained. Surface areas of glass samples are determined by the B. E. T. method with ethylene adsorption. It has been estimated that the adsorption of water vapour on glass surfaces in the range 10
-5 -- 10
-6 mm Hg is not a simple physical one, and that the amounts adsorbed on lead bolosilicate glass are less than on soda lime glass.
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