Journal of Materials Life Society
Online ISSN : 2185-7016
Print ISSN : 1346-0633
ISSN-L : 1346-0633
Volume 32, Issue 2
Displaying 1-3 of 3 articles from this issue
Short Reviews
Original Paper
  • Makiko MIURA, Yukio KITADA, Shogo YAMANE, Hideaki HAGIHARA, Hiroaki SA ...
    2020 Volume 32 Issue 2 Pages 40-45
    Published: May 31, 2020
    Released on J-STAGE: April 22, 2023
    JOURNAL FREE ACCESS

    Polypropylene (PP) is used for automotive parts due to its excellent properties such as toughness, flexibility, lightweight property and heat resistance. Antioxidants are generally added to PP and the concentration of antioxidants in PP generally decreases under thermal oxidative conditions, then its physical properties degrade due to the structural changes of polymer. Chemiluminescence (CL) measurement has been attracting attention as a method to detect oxidation occurring in polymer materials rapidly and simply. There were some reports on investigation of thermal oxidative degradation of PP using CL measurements, however further investigation is required in the cases of polymer materials that contain multiple kinds of antioxidants. In this study, we performed CL measurements at 150°C under oxygen atmosphere for PP added with a combination of phenolic, phosphate and thioether antioxidants. The results were compared with the residual antioxidants in PP heated at 150°C under air. Here the relationship between the reduction of antioxidants and CL measurements was investigated from the results in the cases of PP containing multiple kinds of antioxidants.

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