Thermodynamic simulations of crystallization differentiation using “Rhyolite-MELTS” program are performed for a relatively undifferentiated basaltic melt from Fuji Volcano to examine the relationship between viscosity and SiO
2 content of melt. The relations between viscosities and SiO
2 contents of initially H
2O-rich melts, with initial melt H
2O contents >~2wt.%, are consistent with the melt viscosity scale (MVS) proposed by Takeuchi (2015). However, viscosities of initially H
2O-poor melts, with initial melt H
2O content <~2wt.%, are larger than those predicted by MVS. The deviation from MVS occurs during the early stage of crystallization characterized by increases of FeO* and TiO
2 contents without significant increase of SiO
2 content in melt, due to absence of Fe-Ti oxide minerals in crystallized phases. In the middle stage of crystallization characterized by increase of SiO
2 content and decreases of FeO* and TiO
2 contents, chiefly due to crystallization of Fe-Ti oxide minerals, the melt viscosity-SiO
2 content relations are almost parallel with MVS. Therefore, once melt viscosity deviates from MVS, it remains larger than MVS even the melt H
2O content becomes >2wt.%, suggesting that melt H
2O content is not necessarily an adequate criterion for judging whether MVS is applicable or not. Alternatively, we propose new criteria for MVS application based on SiO
2-Al
2O
3-FeO*-TiO
2 relation of melt, which is useful for a melt sample of unknown H
2O content.
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