Identification of Al(III) Species in a Solution Containing Equimolar Concentrations of Al(III) and Citric Acid Using Varying-Temperature ²⁷Al NMR Spectrometry

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²⁷Al NMR spectra of an equimolar (10 mM) Al(III)-citrate system were obtained at different temperatures. The linewidths of the signals decreased in the spectra recorded at elevated temperatures, which enabled us to unequivocally identify the resonance lines. From the spectrum recorded at 65°C, a mononuclear Al(III)-citrate complex was identified at a solution pH of 3.0 in addition to trinuclear Al(III)-citrate complex, which dominated at pH 4.0.