Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
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The Liquid-Liquid Extraction Using Hydrophilic Solvents Occluded to an Oil-Adsorbent as an Organic Phase: Extraction of 8-Quinolinolato Complexes of Alkaline Earth Metals into Tetrahydrofuran
Kaoru FUJINAGASetsuko SUITOUYasushi SEIKEMinoru OKUMURA
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2005 年 21 巻 3 号 p. 341-343

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In order to use a hydrophilic solvent as an organic phase in liquid-liquid extraction by retaining it to a solid support, the occlusion and desorption of nine hydrophilic solvents, such as methanol, to three kinds of commercially available oil-adsorbent were examined. The combination of tetrahydrofuran and WOSEP made by fibrous polypropylene was finally selected, and was subjected to the extraction of alkaline earth metals with 8-quinolinol. It was proved that Mg2+, Ca2+, and Sr2+ ions could be successfully extracted into the tetrahydrofuran phase in the form of 8-quinolinolato complexes, which could not be extracted into CHCl3.
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© 2005 by The Japan Society for Analytical Chemistry
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