Synthesis of <small>D</small>-Trigalacturonic Acid Methylglycoside and Conformational Comparison with Its Sulfur Analogue

Kazunori YAMAMOTO; Yu SATO; Ayumi ISHIMORI; Kazuo MIYAIRI; Toshikatsu OKUNO; Nobuaki NEMOTO; Hiroki SHIMIZU; Shunichi KIDOKORO; Masaru HASHIMOTO

doi:10.1271/bbb.80160

Organic Chemistry Regular Papers

Synthesis of D-Trigalacturonic Acid Methylglycoside and Conformational Comparison with Its Sulfur Analogue

Kazunori YAMAMOTO, Yu SATO, Ayumi ISHIMORI, Kazuo MIYAIRI, Toshikatsu OKUNO, Nobuaki NEMOTO, Hiroki SHIMIZU, Shunichi KIDOKORO, Masaru HASHIMOTO

著者情報

Kazunori YAMAMOTO
Faculty of Agriculture and Life Science, Hirosaki University
Yu SATO
Faculty of Agriculture and Life Science, Hirosaki University
Ayumi ISHIMORI
Faculty of Agriculture and Life Science, Hirosaki University
Kazuo MIYAIRI
Faculty of Agriculture and Life Science, Hirosaki University
Toshikatsu OKUNO
University of Akita Nursing and Welfare
Nobuaki NEMOTO
JEOL Ltd.
Hiroki SHIMIZU
Drug-Seeds Discovery Research Laboratory, National Institute of Advanced Industrial Science and Technology (AIST)
Shunichi KIDOKORO
Department of Bioengineering, Nagaoka University of Technology
Masaru HASHIMOTO
Faculty of Agriculture and Life Science, Hirosaki University

キーワード: trigalacturonic acid, sulfur-substituted analogue, endo-polygalacturonase 1, NOE

ジャーナルフリー

2008 年 72 巻 8 号 p. 2039-2048

DOI https://doi.org/10.1271/bbb.80160

View "Advance Publication" version (August 7, 2008).

詳細

抄録

D-Trigalacturonic acid methylglycoside (3) was synthesized to evaluate the previously synthesized sulfur analogue 1 by comparison. The NOE experiments revealed that both 3 and 1 took on a similar conformation around their glycosyl linkage.

責任著者(Corresponding author)

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